1, 7-Dithioxo systems. Reaction of bis (5, 5-dimethyl-3-thioxo-cyclohex-1-en-1-yl) sulfide with amines

LV Timokhina, OV Sokol'nikova, LV Kanitskaya…

Index: Timokhina; Sokol'nikova; Kanitskaya; Yashchenko; Voronkov Russian Journal of Organic Chemistry, 2008 , vol. 44, # 4 p. 532 - 535

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Citation Number: 2

Abstract

Abstract Reactions of amines (N, N-dimethylethane-1, 2-diamine, benzylamine, aniline) with bis (5, 5-dimethyl-3-thioxocyclohex-1-en-1-yl) sulfide result in cleavage of the sulfide bond and formation of the corresponding 3-amino-5, 5-dimethylcyclohex-2-ene-1-thiones. Aminolysis of bis (5, 5-dimethyl-3-oxocyclohex-1-en-1-yl) sulfide occurs at the carbonyl groups with conservation of the divinyl sulfide fragment.