Journal of the American Chemical Society

Quaternary methylsulfonylammonium salts. New reagents for mesylation. Mechanism of hydrogen multiexchange in sulfene reactions

JF King, JR du Manoir

Index: King,J.F.; du Manoir,J.R. Journal of the American Chemical Society, 1975 , vol. 97, p. 2566 - 2567

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Citation Number: 15

Abstract

Figure 1. gree of removal was nearly attained in 30 min. Mo-(C0) sads reacts similarly. Thus, at loo', Mo (C0) 6/A1203 decomposes to Mo-(C0) sads which further decomposes to Mo (CO), ads. The second step is favored by low PCO and prevented by Pco greater than 0.07 atm. Mo (CO), ads can be nearly completely reconverted to Mo (CO)~+*/-AI203 by sweeping with carbon monoxide at 100'. The activity5 of both fresh and used Mo (CO) 3ads catalysts ...