Liebigs Annalen der Chemie

Synthesis of aryl azide analogues of insect juvenile hormones as reagents for the photoaffinity labeling of juvenile hormone binding proteins

HP Stupp, MG Peter

Index: Stupp, Hans-Peter; Peter, Martin G. Liebigs Annalen der Chemie, 1987 , p. 327 - 331

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Citation Number: 2

Abstract

Abstract The azidophenyl 6, 7-epoxygeranyl ethers rac-4c and rac-4d and the azidobenzoate rac-6 were synthesized. p-Azidophenyl 6, 7-epoxygeranyl ether (rac-4c) shows a high affinity to the juvenile hormone binding protein of the migratory locust, Locusta migratoria. Fast photolysis is observed upon irradiation at 254 nm and at 300 nm. It is proposed that rac-4c is useful as a new reagent for the study of juvenile hormone binding ...