2??and 3??Monohalogenated BODIPY Dyes and Their Functionalized Analogues: Synthesis and Spectroscopy

…, T Leemans, N Boens, W Dehaen

Index: Leen, Volker; Leemans, Tom; Boens, Noel; Dehaen, Wim European Journal of Organic Chemistry, 2011 , # 23 p. 4386 - 4396

Full Text: HTML

Citation Number: 47

Abstract

Abstract Starting from appropriately halogenated acylpyrroles, a wide range of reactive 4, 4- difluoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY) derivatives can be obtained. The fluorescent dyes display excellent reactivity in nucleophilic aromatic substitution, transition- metal-catalyzed cross-coupling and copper-catalyzed cycloaddition to azides (click chemistry). The spectral properties of the starting and final difluoroboron dipyrromethenes ...