The Journal of organic chemistry

A tin hydride designed to facilitate removal of tin species from products of stannane-mediated radical reactions

DLJ Clive, J Wang

Index: Clive, Derrick L. J.; Wang, Jian Journal of Organic Chemistry, 2002 , vol. 67, # 4 p. 1192 - 1198

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Citation Number: 67

Abstract

The stannane 1, which is simple to prepare, behaves like the conventional reagents Bu3SnH and Ph3SnH in standard free radical reactions, but with the special characteristic that the tin-containing byproducts are easily and very largely removed by mild hydrolysis (LiOH-water-THF or TsOH-water-THF), which converts them into base-soluble (aqueous NaHCO3) materials. The performance of stannane 1 was evaluated for a range of radical ...