Polyhedron

Synthesis, structure and spectroscopic properties of cobalt (III) complexes with 1-benzoyl-(3, 3-disubstituted) thiourea

S San Tan, AA Al-Abbasi, MIM Tahir, MB Kassim

Index: Tan, Siew San; Al-Abbasi, Aisha A.; Mohamed Tahir, Mohamed Ibrahim; Kassim, Mohammad B. Polyhedron, 2014 , vol. 68, p. 287 - 294

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Citation Number: 11

Abstract

Abstract Reactions of Co (II) acetate with 1-benzoyl-(3-methyl-3-R) thiourea (R= ethyl, propyl, cyclohexyl and phenyl) and 1-benzoyl-(3-ethyl-3-benzyl) thiourea ligands, herein refer to as 1-benzoyl-(3, 3-disubstituted) thiourea, derived from secondary alkyl-and arylamines gave [tris (1-benzoyl-(3, 3-disubstituted) thiourea) cobalt (III)] complexes. The neutral cobalt (III) complexes were afforded through a one-pot reaction between a ...