Electron-transfer-induced valence isomerization of 2, 2'-distyrylbiphenyl

…, K Meerholz, J Heinze, K Muellen

Index: Boehm, Arno; Meerholz, Klaus; Heinze, Juergen; Muellen, Klaus Journal of the American Chemical Society, 1992 , vol. 114, # 2 p. 688 - 699

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Citation Number: 6

Abstract

Summary The results of this work show that the time-resolved 1270-nm IO2 luminescence can be used as an effective probe for the mechanism of photooxygenation reactions. If@ lO2 is affected by substrate, it is necessary to look for substratesensitizer interactions and probe the system further. If only the IO2 lifetime is changed by substrate, a pure IO2 Type I1 mechanism is involved. This work also suggests that the production of IO2 from sensitizers ...