Iridium??Catalyzed Mizoroki–Heck??Type Reaction of Organosilicon Reagents

T Koike, X Du, T Sanada, Y Danda…

Index: Koike, Tooru; Du, Xiaoli; Sanada, Tomoyuki; Danda, Yasuaki; Mori, Atsunori Angewandte Chemie - International Edition, 2003 , vol. 42, # 1 p. 89 - 92

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Citation Number: 58

Abstract

Iridium-catalyzed CĀC bond-forming reactions have recently attracted much attention.[1] However, the reaction with main group organometallic reagents containing elements such as boron, tin, and silicon has not been demonstrated so far. Although carbonącarbon bond formation with such main group reagents with an α, β-unsaturated carbonyl compound has been reported recently to undergo a MizorokiąHeck-type or conjugate addition reaction ...