Synthesis of bis (2-haloethyl) selenides by reaction of selenium dihalides with ethylene

…, EO Kurkutov, MV Musalov, SV Amosova

Index: Potapov; Kurkutov; Musalov; Amosova Russian Journal of Organic Chemistry, 2014 , vol. 50, # 2 p. 291 - 292 Zhurnal Organicheskoi Khimii, 2014 , vol. 50, # 2 p. 298 - 299,2

Full Text: HTML

Citation Number: 1

Abstract

Introduction in the organic synthesis of new electrophilic reagents, selenium dichloride and dibromide, made it possible to develop efficient methods of preparation of new organoselenium compounds [1–4]. Based on reactions of selenium dihalides with acetylene a new stereoselective method was developed for the synthesis of (Е, Е)-bis (2-halovinyl) selenides [2]. The reaction of selenium dihalides with alkenes proceeds stereoselectively ...