New sources of “active” halogen bis (dialkylamide) hydrogen dibromobromates, efficient reagents for destruction of ecotoxicants

TM Prokop'eva, VA Mikhailov, MK Turovskaya…

Index: Prokop'eva; Mikhailov; Turovskaya; Karpichev; Burakov; Savelova; Kapitanov; Popov Russian Journal of Organic Chemistry, 2008 , vol. 44, # 5 p. 637 - 646

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Citation Number: 3

Abstract

Abstract Bis (dialkylamide) hydrogen dibromobromates were synthesized and their reactivity was investigated in decomposition of diethylphosphonic, diethylphosphoric, and 4- toluenesulfonic acids 4-nitrophenyl esters. The nucleophilic reactivity of a typical α- nucleophile, hypobromite ion, is independent of the source of the active bromine. The cetyltrimethylammonium dibromobromate is a unique reagent for destruction of ...