e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Conversion of phosphinic into phosphinous esters through nickelocene reduction–complexation of phosphinothioic O-esters. A new synthesis of carbon–phosphorus …
F Mathey, F Mercier
Index: Mathey, Francois; Mercier, Francois Journal of the Chemical Society, Chemical Communications, 1980 , # 4 p. 191 - 192
A new procedure for reducing a phosphinate (LO) into the corresponding phosphinite (L) includes the following steps: LO→ LS→ CpNi (I) L→ NiL4→ L (Cp= cyclopentadiene); such a scheme is illustrated by the syntheses of 2-phenyl-1, 2-oxaphospholane and 2- phenylisophosphindoline 2-oxide.
