Coordination chemistry of 2, 6-bis (diphenylphosphorylmethyl)-4-methylphenol

…, SV Matveev, PV Petrovskii, EE Nifant'ev

Index: Matveeva; Matrosov; Starikova; Bodrin; Matveev; Petrovskii; Nifant'ev Russian Chemical Bulletin, 2005 , vol. 54, # 11 p. 2519 - 2534

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Abstract

Abstract The trifunctional ligand, 2, 6-bis (diphenylphosphorylmethyl)-4-methylphenol (L 2), forms complexes with cerium (III) nitrate having a ligand to metal ratio of 1: 1, 2: 1, and 3: 1. The structures of these complexes in the solid state and in solution were studied by X-ray diffraction, IR and NMR (1 H and 31 P) spectroscopy, and conformational analysis (molecular mechanics). The 2: 1 complexes of L 2 with lanthanum (III) and neodymium (III) ...