e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Model compound studies of the β-O-4 linkage in lignin: absolute rate expressions for β-scission of phenoxyl radical from 1-phenyl-2-phenoxyethanol-1-yl radical
PH Kandanarachchi, T Autrey…
Index: Kandanarachchi, Pramod H; Autrey, Tom; Franz, James A The Journal of organic chemistry, 2002 , vol. 67, # 23 p. 7937 - 7945
Arrhenius rate expressions were determined for β-scission of phenoxyl radical from 1-phenyl- 2-phenoxyethanol-1-yl, PhC (OH) CH2OPh (V). Ketyl radical V was competitively trapped by thiophenol to yield PhCH (OH) CH2OPh in competition with β-scission to yield phenoxyl radical and acetophenone. A basis rate expression for hydrogen atom abstraction by sec- phenethyl alcohol, PhC (OH) CH3, from thiophenol, log (k abs/M-1 s-1)=(8.88±0.24)-(6.07 ...
