Convenient one pot synthesis of phosphonites and H-phosphinates

I Petnehazy, ZM Jászay, A Szabó…

Index: Petnehazy, Imre; Jaszay, Zsuzsa M.; Szabo, Andrea; Everaert, Kinga Synthetic Communications, 2003 , vol. 33, # 10 p. 1665 - 1674

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Citation Number: 13

Abstract

A convenient and simple one-pot method is described for the synthesis of phosphonites [RP(OEt) 2 , 1] and H-phosphinates [HP(O)R(OEt), 2] from triethyl phosphite and appropriate Grignard reagents. ... A convenient and simple one-pot method is described for the synthesis of phosphonites [RP(OEt) 2 , 1] and H-phosphinates [HP(O)R(OEt), 2] from triethyl phosphite and appropriate Grignard reagents. ... Despite the importance of 1 and 2 as precursors, ...