Journal of the American Chemical Society

Construction of linear-fused tricyclopentanoids by intramolecular [6+ 2] cycloadditions of fulvenes with enamines

TC Wu, KN Houk

Index: Wu,T.C.; Houk,K.N. Journal of the American Chemical Society, 1985 , vol. 107, p. 5308

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Citation Number: 36

Abstract

The synthesis of linearly fused tricyclopentanoids is a popular subject for the demonstration of modern synthetic methods.'Among the two-score methods applied to the preparation of hirsutene and its more elaborate relatives, 2 those reported by the groups of Little and Curran involve the simultaneous annulation of two new five-membered rings onto a preexisting~ yclopentane.~ We have developed a similar strategy based upon ...