Oxidative De??aromatization of para??Alkyl Phenols into para??Peroxyquinols and para??Quinols Mediated by Oxone as a Source of Singlet Oxygen

MC Carreño, M González??López…

Index: Carreno, M. Carmen; Gonzalez-Lopez, Marcos; Urbano, Antonio Angewandte Chemie - International Edition, 2006 , vol. 45, # 17 p. 2737 - 2741

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Citation Number: 62

Abstract

The controlled oxidation of organic compounds is particularly important for aromatic derivatives bearing alkyl substituents that are prone to suffer over-oxidation. The search for selective methods to effect the oxidative de-aromatization of para-alkyl phenols into 4-alkyl-4- hydroperoxy-2, 5-cyclohexadienones (para-peroxyquinols) and 4-alkyl-4-hydroxy-2, 5- cyclohexaACHTUNGTRENNUNGdienones (para-quinols) is of huge interest because of ...