Tetrahedron

Versatile desilylative cross-coupling of silyl enol ethers and allylic silanes via oxovanadium-induced chemoselective one-electron oxidation

T Hirao, T Fujii, Y Ohshiro

Index: Hirao, Toshikazu; Fujii, Takashi; Ohshiro, Yoshiki Tetrahedron, 1994 , vol. 50, # 34 p. 10207 - 10214

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Citation Number: 28

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The chemoselective cross-coupling of silyl enol ethers and allylic silanes to γ,δ-unsaturated ketones is achieved by the oxovanadium (V)-induced oxidative desilylation of the more readily oxidizable organosilicon compounds. ... The title oxidative intermolecular carbon-carbon bond ...

~63%

~46%

~64%

~0%

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