Asymmetric synthesis by chiral ruthenium complexes: X. Enantioface discriminating isomerization of olefins

…, P Frediani, G Menchi, C Botteghi, M Marchetti

Index: Matteoli, Ugo; Bianchi, Mario; Frediani, Piero; Menchi, Gloria; Botteghi, Carlo; Marchetti, Mauro Journal of Organometallic Chemistry, 1984 , vol. 263, # 2 p. 243 - 246

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Citation Number: 19

Abstract

Prochiral 3-methyl-5-phenylpent-Zene has been isomerized in the presence of H,Ru,(CO),[( -)-DIOP],, both in the presence and in the absence of hydrogen. (S)-( + )-l-Phenyl-3-methylpent -1-ene was formed as the consequence of an enan- tioface differentiating process. ... In a previous paper we have reported that olefin isomerization is concurrent with its hydrogenation when using H4Ru4(C0)s[( -)-DIOP], [l]. Isomerization may ... In order to test whether an enantioface ...