Chemistry Letters

New efficient palladium-catalyzed perfluoroalkylation of carbon-carbon multiple bonds with F-alkyl iodides. An expedient route to F-alkylated alkyl and alkenyl iodides

T Ishihara, M Kuroboshi, Y Okada

Index: Ishihara, Takashi; Kuroboshi, Manabu; Okada, Yoshiji Chemistry Letters, 1986 , p. 1895 - 1896

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Citation Number: 16

Abstract

A variety of alkenes and alkynes efficiently undergo the perfluoroalkylation with F-alkyl iodides in the presence of a catalytic amount of tetrakis (triphenylphosphine) palladium (0) in hexane to give good yields of the corresponding F-alkylated alkyl and alkenyl iodides, respectively.