Bulletin of the Chemical Society of Japan

Synthesis and Properties of Bis (oxybis (methylenethio)) tetrathiafulvalene and Its Sulfur Analog:. PI.-Donors for Organic Metals.

H Müller, Y Ueba

Index: Mueller, Harald; Ueba, Yoshinobu Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 6 p. 1773 - 1777

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Citation Number: 13

Abstract

Bis [oxybis (methylenethio)] tetrathiafulvalene (BOBMT-TTF) and bis [thiobis (methylenethio)] tetrathiafulvalene (BTBMT-TTF) were synthesized in two steps starting from 1, 3, 4, 6- tetrathiapentalene-2, 5-dione. The electrochemical and donor properties of both compounds are discussed. BOBMT-TTF forms a highly conducting charge transfer complex with TCNQ (σ RT 10 S cm− 1).