Chemical Communications

Zinc-promoted direct amination of nitropyridines with methoxyamine via vicarious nucleophilic substitution

S Seko, K Miyake

Index: Seko, Shinzo; Miyake, Kunihito Chemical Communications, 1998 , # 15 p. 1519 - 1520

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Citation Number: 21

Abstract

... NO2 R H2N + NH2OMe ButOK, room temp. ZnCl2 2 1 Zinc-promoted direct amination of nitropyridines with methoxyamine via vicarious nucleophilic substitution Shinzo Seko*† and Kunihito Miyake Organic Synthesis Research Laboratory, Sumitomo Chemical Co., Ltd, Tsukahara, Takatsuki, Osaka 569-1093, Japan ... 9 TC Bissot, RW Parry and DH Campbell, J. Am. Chem. Soc., 1957, 79, 796. 10 S. Seko and N. Kawamura, J. Org, Chem., 1996, 61, 442. ...