e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Orthoamide, XXXIII. Beiträge zur Chemie von Bis (dialkylamino) acetonitrilen

W Kantlehner, R Baur…

Index: Kantlehner, Willi; Baur, Richard; Bredereck, Hellmut Liebigs Annalen der Chemie, 1980 , # 3 p. 358 - 371

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Citation Number: 2

Abstract

Abstract Bis (dialkylamino) acetonitrile 2a—d reagieren mit Acetylchlorid und Antimonpentachlorid zu N, N, N′, N′-Tetraalkylformamidinium-hexachloroantimonaten 5a— d. Bei der Einwirkung von p-Nitrophenol auf 2a, b entstehen die N, N, N′, N′- Tetraalkylformamidiniumsalze 8a, b. Aromatische Aldehyde 11 setzen sich mit den Verbindungen 2 zu Aryl (dialkylamino) acetonitrilen 12 um. Phenylisothiocyanat bildet mit ...

bis(dimethylamino)acetonitrile Structure

bis(dimethylami...

4-Chlorobenzaldehyde Structure

4-Chlorobenzaldehyde

~64%

4-Chloro-α-(dimethylamino)benzeneacetonitrile Structure

4-Chloro-α-(dim...

N,N-Dimethylformamide Structure

N,N-Dimethylfor...

Bis(1-pyrrolidinyl)acetonitril Structure

Bis(1-pyrrolidi...

4-Methoxybenzaldehyde Structure

4-Methoxybenzal...

~0%

1-formylpyrrolidine Structure

1-formylpyrrolidine

1-Pyrrolidineacetonitrile,a-(4-methoxyphenyl)- Structure

1-Pyrrolidineac...

Bis(1-pyrrolidinyl)acetonitril Structure

Bis(1-pyrrolidi...

4-Methoxybenzaldehyde Structure

4-Methoxybenzal...

~61%

1-formylpyrrolidine Structure

1-formylpyrrolidine

1-Pyrrolidineacetonitrile,a-(4-methoxyphenyl)- Structure

1-Pyrrolidineac...

Bis(1-piperidinyl)acetonitril Structure

Bis(1-piperidin...

4-Methoxybenzaldehyde Structure

4-Methoxybenzal...

~67%

Formylpiperidine Structure

Formylpiperidine

1-Piperidineacetonitrile,a-(4-methoxyphenyl)- Structure

1-Piperidineace...

Benzoyl cyanide Structure

Benzoyl cyanide

bis(dimethylamino)acetonitrile Structure

bis(dimethylami...

~89%

1N1&VR Structure

bis(dimethylamino)acetonitrile Structure

bis(dimethylami...

P-NITROPHENYLACETATE Structure

P-NITROPHENYLACETATE

~0%

N,N-Dimethylacetamide Structure

N,N-Dimethylace...

p-Nitrophenol-N,N,N',N'-tetramethylformamidinium-(p-nitrophenolat) Structure

p-Nitrophenol-N...

bis(dimethylamino)acetonitrile Structure

bis(dimethylami...

Benzaldehyde Structure

~0%

Benzeneacetonitrile, a-(dimethylamino)- Structure

Benzeneacetonit...

N,N-Dimethylformamide Structure

N,N-Dimethylfor...

bis(dimethylamino)acetonitrile Structure

bis(dimethylami...

4-Chlorobenzaldehyde Structure

4-Chlorobenzaldehyde

~0%

4-Chloro-α-(dimethylamino)benzeneacetonitrile Structure

4-Chloro-α-(dim...

N,N-Dimethylformamide Structure

N,N-Dimethylfor...

bis(dimethylamino)acetonitrile Structure

bis(dimethylami...

4-Methoxybenzaldehyde Structure

4-Methoxybenzal...

~0%

Dimethylamino(4-methoxyphenyl)acetonitril Structure

Dimethylamino(4...

N,N-Dimethylformamide Structure

N,N-Dimethylfor...

bis(dimethylamino)acetonitrile Structure

bis(dimethylami...

p-Tolualdehyde Structure

~0%

α-Dimethylamino-α-(4-methylphenyl)-acetonitrile Structure

α-Dimethylamino...

N,N-Dimethylformamide Structure

N,N-Dimethylfor...

Bis(1-piperidinyl)acetonitril Structure

Bis(1-piperidin...

Benzaldehyde Structure

~69%

Formylpiperidine Structure

Formylpiperidine

1-Piperidineacetonitrile,a-phenyl- Structure

1-Piperidineace...

Orthoamide, XVII. Reaktionen von Dimethylamino??alkoxy??acet...

[Bredereck,H. et al. Chemische Berichte, 1971 , vol. 104, p. 932 - 940]