New phenoxyketimine titanium complexes: combining isotacticity and living behavior in propylene polymerization

AF Mason, GW Coates

Index: Mason, Andrew F.; Coates, Geoffrey W. Journal of the American Chemical Society, 2004 , vol. 126, # 50 p. 16326 - 16327

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Citation Number: 143

Abstract

A series of titanium bis (phenoxyketimine) olefin polymerization catalysts were synthesized and screened for propylene polymerization. The phenoxyketimine ligands contain pentafluorophenyl N-aryl groups and ortho-phenol substituents of varying size. Catalysts with ortho-phenol substituents of intermediate size produce living, substantially isotactic polypropylene. The living nature of these catalyst systems is demonstrated through the ...

Reactions ofN-pentafluorophenylcarbonimidoyl dichloride with...

[Petrova, T. D.; Lolesnikova, I. V.; Mamatyuk, V. I.; Vetchinov, V. P.; Platonov, V. E.; et al. Russian Chemical Bulletin, 1993 , vol. 42, # 9 p. 1540 - 1546 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 9 p. 1605 - 1611]

Polyfluoroarylcarbonimidoyl dichlorides and chlorides. A new...

[Savchenko, T. I.; Kolesnikova, I. V.; Petrova, T. D.; Platonov, V. E. Journal of Fluorine Chemistry, 1983 , vol. 22, p. 439 - 458]

… of N-(Perfluorophenyl) carbonimidoyl Dichloride with Aroma...

[Petrova; Platonov Russian Journal of Organic Chemistry, 2005 , vol. 41, # 2 p. 218 - 226]