Thermolysis of 3-methyl-3-alkyl-1, 2-dioxetanes: steric effects on the activation parameters

AL Baumstark, T Dunams, LH Catalani…

Index: Baumstark, Alfons L.; Dunams, Tambra; Catalani, Luiz H.; Bechara, Etelvino J. H. Journal of Organic Chemistry, 1983 , vol. 48, # 21 p. 3713 - 3716

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Citation Number: 5

Abstract

Results 3-Methyl-3-ethyl-l, 2-dioxetane (l), 3-methyl-3-(1-propyl)-1, 2-dioxetane (2), 3-methyl- 3-(l-butyl)-l, 2-dioxe-tane (3), 3-methyl-3-(2-propyl)-1, 2-dioxetane (4), and 3-methyl-3-tert- butyl-1, 2-dioxetane (5) were synthesized in 510% yield by closure of the bromo hydroperoxides in CC14 with base at 0" C. The dioxetanes, isolated by low-