REAKTIONEN VON PHOSPHOR (III)-TRIMETHYLSILYLESTERN UND ESTERAMIDEN MIT ORTHOCHINONEN; SYNTHESE NEUER 2-TRIMETHYLSILOXYPHENYL …

…, A Fischer, PG Jones, R Schmutzler

Index: Well, Michael; Fischer, Axel; Jones, Peter G.; Schmutzler, Reinhard Phosphorus, Sulfur and Silicon and the Related Elements, 1992 , vol. 71, # 1 p. 143 - 156

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Citation Number: 9

Abstract

Abstract The reaction of R2POSiMe3 [R [dbnd] Me, Ph, Me2N, O'Pr] with 3, 5-di-tert-butyl-o- benzoquinone led to the 2-trimethylsiloxyphenyl phosphoric derivatives 1–4. In the case of the trimethylsilylphosphites (RO) 2POSiMe3 [R [dbnd] Me, Et, Ph], the benzo-1, 3, 2- dioxaphospholines 5–7 were formed by elimination of the corresponding silylethers ROSiMe3. The reaction of R2POSiMe3 [R [dbnd] Me, Me2N, OMe, OiPr, OPh] with ...