Synthesis, textural characterization, differential scanning calorimetry, and dilatometry studies are carried out on a new homologous series of N-(pn-alkoxy benzylidene)-pn-pentyloxy anilines (nO. O5) where n= 1–18. The lower homologues of this series (n= 1–5) and a higher homologue (n= 16) exhibit monotropic Liquid Crystal (LC) phase. The other members of the series show enantiotropic LC phases, while 18O. O5 is a nonliquid crystal. The ...