Tetrahedron letters

Polyfunctional carbosilanes and organosilicon compounds. Synthesis via Grignard reactions

DJ Brondani, RJP Corriu, S El Ayoubi, JJE Moreau…

Index: Brondani, Dalci J.; Corriu, Roben J. P.; El Ayoubi, Sabar; Moreau, Joel J. E.; Man, Michel Wong Chi Tetrahedron Letters, 1993 , vol. 34, # 13 p. 2111 - 2114

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Citation Number: 41

Abstract

Abstract The THF solutions of (triethoxysilyl) methyl magnesium chloride are stable at low temperatures. At 20 C, the Grignard reagent underwent intermolecular condensation, providing a simple synthesis of cyclic carbosilanes derivatives. The cross-coupling reaction with organic halides also afforded a facile route to a variety of trifunctional organosilicon compounds.