Fullerene ylidene malonate supramolecular triads

L Garlaschelli, I Messina, D Pasini…

Index: Garlaschelli, Luigi; Messina, Ivano; Pasini, Dario; Righetti, Pier Paolo European Journal of Organic Chemistry, 2002 , # 20 p. 3385 - 3392

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Citation Number: 15

Abstract

Abstract This paper describes the synthesis and characterization of novel covalently bound fullerene ylidene malonate dyads in which the linker between the two units is a di-, tri-, or tetraethylene glycol unit. The synthesis involves a stepwise, convergent addition of the two components to bis (malonate crown ethers) of increasing overall dimensions through (i) Knoevenagel condensation with (dimethylamino) benzaldehyde and (ii) subsequent ...