Titanium Tetrachloride-Induced Three-Component Coupling Reaction of α-Haloacylsilane, Allylsilane, and Carbonyl Compound

Y Horiuchi, K Oshima, K Utimoto

Index: Horiuchi, Yoshihiro; Oshima, Koichiro; Utimoto, Kiitiro Journal of Organic Chemistry, 1996 , vol. 61, # 13 p. 4483 - 4486

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Citation Number: 9

Abstract

There has been considerable interest in the chemistry of acylsilanes1 and many procedures have been developed for the preparation of many functionalized acylsilanes. 2 Only a few reports, however, have been published for the synthesis of R-haloacylsilanes. 3 Recently we have reported a facile approach to R-haloacylsilanes based on the rearrangement of R- haloepoxysilane and their use for triethylborane-mediated Reformatsky type reaction ...