Tetrafluorothiirane

WR Brasen, HN Cripps, CG Bottomley…

Index: Brasen,W.R. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 4188 - 4193

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Citation Number: 27

Abstract

VI11 IX of radicals are more electrophilic than alkyl radical^^^^ and attack of a radical on saturated carbon rather than on a peripheral atom is rare, it is probable that radicals in general attack the thiirane at sulfur. Another unusual example of radical attack on sulfur in a perfluorinated monosulfide was encountered during copolymerizations of IV with tetrafluoroethylene. A sizeable proportion of octafluorothiolane (X) was formed by a ...