Tetrahedron letters

Syntheses of marine ochtodane antifeedants via hydrolytic dehalogenation

Z Joseph, BM Howard

Index: Zegarski, Joseph; Howard, Bruce M. Tetrahedron Letters, 1985 , vol. 26, # 11 p. 1363 - 1366

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Citation Number: 7

Abstract

Abstract The syntheses of five naturally occurring antifeedants of the ochtodane ring system (1-ethyl-3, 3-dimethylcyclohexane), previously isolated from the marine red alga Ochtodes crockeri, are reported. A key synthetic step involves the hydrolytic debromination of 6-bromo- 1, 4-ochtodien-3-ol.