Palladium/Me3SiOTf-Catalyzed Bis-silylation of α, β-Unsaturated Carbonyl Compounds without Involving Oxidative Addition of Disilane

…, S Tomiyasu, M Morita, H Kurosawa

Index: Ogoshi, Sensuke; Tomiyasu, Sadayuki; Morita, Masaki; Kurosawa, Hideo Journal of the American Chemical Society, 2002 , vol. 124, # 39 p. 11598 - 11599

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Citation Number: 52

Abstract

In the presence of a catalytic amount of Me3SiOTf and palladium (0), the addition of disilane to α, β-unsaturated carbonyl compounds proceeds under very mild conditions via η3- siloxyallylpalladium generated by the reaction of enone, enal, or aromatic aldehyde with palladium and Me3SiOTf.