Efficient Silver??Catalyzed Regio??and Stereospecific Aziridination of Dienes

J Llaveria, Á Beltrán, M Díaz??Requejo…

Index: Llaveria, Josep; Beltran, Alvaro; Diaz-Requejo, M. Mar; Perez, Pedro J.; Matheu, M. Isabel; Castillon, Sergio Angewandte Chemie - International Edition, 2010 , vol. 49, # 39 p. 7092 - 7095

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Citation Number: 47

Abstract

The synthesis of aziridine derivatives through metal-mediated nitrene addition reactions to olefins [Eq.(1)] has been extensively developed in the last decades; quantitative conversions as well as complete enantioselection have been already described.[1, 2] However, in spite of the large number of reports related to the alkene aziridination reaction by this method and the synthetic interest of vinylaziridines,[3] only few have dealt with conjugated dienes as ...