Electrochromics by intramolecular redox switching of single bonds

S Hünig, CA Briehn, P Bäuerle…

Index: Huenig, Siegfried; Aldenkortt, Sven; Baeuerle, Peter; Briehn, Christoph A.; Schaeferling, Michael; Perepichka, Igor F.; Stalke, Dietmar; Walfort, Bernhard European Journal of Organic Chemistry, 2002 , # 10 p. 1603 - 1614

Full Text: HTML

Citation Number: 25

Abstract

Abstract Two moieties of mono-and trimethincyanines as well as those of styryl dyes were connected by a saturated alkyl tether made from compounds 3 a–c, 5, 7, and 9 a, b. In most cases, cyclic voltammetry and spectroelectrochemistry for these dyes together with the data for their monomeric models 4, 6, 8, and 10 reveal electrochemically irreversible transfer of two electrons but chemically reversible reaction and discoloration both on reduction and ...