Tetrahedron

Development of non-symmetric thiophene-fused BODIPYs

XD Jiang, H Zhang, Y Zhang, W Zhao

Index: Jiang, Xin-Dong; Zhang, Houjun; Zhang, Yuanlin; Zhao, Weili Tetrahedron, 2012 , vol. 68, # 47 p. 9795 - 9801,7

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Citation Number: 32

Abstract

A series of non-symmetric BODIPYs containing thieno [3, 2-b] pyrrole moiety were synthesized in 21–63% yields. The absorption and emission maxima covered from the visible green to red region (λabs= 532–647nm; λem= 547–664nm; Φf= 0.19–0.45). X-ray analysis indicated that the S–C bond lengths were shorter than those of thienopyrrole and thienohelicene by 0.03–0.05 Å. The crystal packing pattern suggested that strong π–π ...