Tetrahedron letters

Deoxygenation of oxiran compounds to olefins by [Fe 4 S 4 (SC 6 H 5) 4] 2− in the presence of NaBH 4

T Itoh, T Nagano, M Sato, M Hirobe

Index: Itoh, Takashi; Nagano, Tetsuo; Sato, Mitsuo; Hirobe, Masaaki Tetrahedron Letters, 1989 , vol. 30, # 46 p. 6387 - 6388

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Citation Number: 26

Abstract

The dianion complex [Fe 4 S 4 (SC 6 H 5 ) 4 ] 2− caused deoxygenation reaction of oxiran compounds to olefins in the presence of NaBH 4 . The reduced form [Fe 4 S 4 (SR) 4 ] 3− was suggested as an active reductant in this reaction. ... Present address: School of Pharmaceutical Sciences, Showa University, Hatanodai, Shinagawa-ku, Tokyo 142, Japan. ... Cookies are used by this site. To decline or learn more, visit our Cookies page.