Plasticity of the Nickel (II) Coordination Environment in Complexes with Hemilabile Phosphino Thioether Ligands

…, AM Spokoyny, MR Jones, AA Sarjeant…

Index: MacHan, Charles W.; Spokoyny, Alexander M.; Jones, Matthew R.; Sarjeant, Amy A.; Stern, Charlotte L.; Mirkin, Chad A. Journal of the American Chemical Society, 2011 , vol. 133, # 9 p. 3023 - 3033

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Citation Number: 10

Abstract

A series of homoligated Ni (II) complexes formed from two phosphino thioether (P, S) chelating ligands has been synthesized and characterized. Interestingly, this included octahedral Ni (II) complexes which, unlike previously characterized d8 Rh (I), Pt (II), and ...