ortho??Directed Metathetical Fluoride/Amide Exchange in (Pentafluorophenyl) amides

…, MV Zabalov, J Sundermeyer, J Lorberth…

Index: Shutov, Pavel L.; Karlov, Sergey S.; Harms, Klaus; Zabalov, Maxim V.; Sundermeyer, Joerg; Lorberth, Joerg; Zaitseva, Galina S. European Journal of Inorganic Chemistry, 2007 , # 36 p. 5684 - 5692

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Citation Number: 3

Abstract

Abstract The indium tris (amide) s [(Et 2 N) 3–n In {N (C 6 F 5)(2-C 5 H 4 N)} n][n= 1 (15), 2 (16) or 3 (9)] have been prepared by treatment of [In (NEt 2) 3] 2 (3) with a stoichiometric amount of (2-C 5 H 4 N)(C 6 F 5) NH (1). The analogous reaction of Bi (NMe 2) 3 (2) with 3 equiv. of amine 1 and the treatment of BiCl 3 (5) with a stoichiometric amount of (2-C 5 H 4 N)(C 6 F 5) NLi (4) both lead to [Bi {N (C 6 F 5)(2-C 5 H 4 N)} 3](10). In contrast, only the ...