Tetrahedron

Approaches to stable cyclopropenyl anions: Tris-1, 2, 3-p-nitrophenylcyclopropene

J Klicic, Y Rubin, R Breslow

Index: Klicic, Jasna; Rubin, Yves; Breslow, Ronald Tetrahedron, 1997 , vol. 53, # 12 p. 4129 - 4136

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Citation Number: 13

Abstract

Tris-1, 2, 3-p-nitrophenylcyclopropene has been synthesized from the tosylhydrazone of an enone, and examined as a precursor of the corresponding cyclopropenyl anion. A precursor of the related trimethylsilylcyclopropene has also been prepared by a series of palladium- catalyzed reactions.