Journal of the American Chemical Society

Bis (trifluoromethyl) dithiophosphinic acid and related derivatives

K Gosling, AB Burg

Index: Gosling,K.; Burg,A.B. Journal of the American Chemical Society, 1968 , vol. 90, p. 2011 - 2015

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Citation Number: 17

Abstract

Abstract: The readily volatile new dithiophosphinic acid (CF3) 2PSzH (mp 14”; bp estd 105”; monomeric, unlike the analogous oxygen compound) has been made by the HzS cleavage of the nonvolatile [(CF3) zPS] zS (presumed), obtained by heating [(CF&P], S with sulfur. Another process, in which (CF&P (S) I is attacked by HzS, depends upon a novel reduction process, liberating iodine. The spontaneous loss of iodine from (CF3), P (S) I was pushed ...