Chemical Communications

Rearrangement of o-(chloromethyldimethylsilyl) phenylmethoxide: evidence for an apical position of the migrating group in a trigonal bipyramid intermediate

YM Hijji, PF Hudrlik, AM Hudrlik

Index: Hijji, Yousef M.; Hudrlik, Paul F.; Hudrlik, Anne M. Chemical Communications, 1998 , # 11 p. 1213 - 1214

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Abstract

... 10 8 9 5a 7 – – Rearrangement of o-(chloromethyldimethylsilyl)phenylmethoxide: evidence for an apical position of the migrating group in a trigonal bipyramid intermediate Yousef M. Hijji,† Paul F. Hudrlik*‡ and Anne M. Hudrlik Department of Chemistry, Howard University, Washington, DC 20059, USA ... The GC–MS showed m/z 178 (15%, M+), 163 (8, M+ 2 Me), 149 (100, M+ 2 Et), 135 (8) and 105 (11). ... 8 YM Hijji, PF Hudrlik, CO Okoro and AM Hudrlik, Synth. ...