European Journal of Organic Chemistry

Palladium??Catalyzed Cross??Coupling Reaction of Functionalized Aryl??and Heteroarylbismuthanes with 2??Halo (or 2??Triflyl) azines and??diazines

P Petiot, A Gagnon

Index: Petiot, Pauline; Gagnon, Alexandre European Journal of Organic Chemistry, 2013 , # 24 p. 5282 - 5289

Full Text: HTML

Citation Number: 7

Abstract

Abstract The palladium-catalyzed cross-coupling of highly functionalized organobismuthanes with 2-halo (or 2-triflyl) pyridines,-pyrimidines,-pyrazines, and- pyridazines is reported. The reaction tolerates numerous functional groups, including aldehydes. The synthesis of a shelf-stable (formylphenyl) bismuth reagent and its use in a cross-coupling reaction is also described.