Chemistry–An Asian Journal

Brominated Methanes as Photoresponsive Molecular Storage of Elemental Br2

K Kawakami, A Tsuda

Index: Kawakami, Kazumitsu; Tsuda, Akihiko Chemistry - An Asian Journal, 2012 , vol. 7, # 10 p. 2240 - 2252

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Citation Number: 4

Abstract

Abstract The photochemical generation of elemental Br 2 from brominated methanes is reported. Br 2 was generated by the vaporization of carbon oxides and HBr through oxidative photodecomposition of brominated methanes under a 20 W low-pressure mercury lamp, wherein the amount and situations of Br 2 generation were photochemically controllable. Liquid CH 2 Br 2 can be used not only as an organic solvent but also for the ...

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