PMA/SiO2-An efficient recyclable heterogeneous catalyst for the synthesis of homoallyl alcohols and amines under solvent-free conditions

…, P Thirupathi, K Suneel, P Sunitha

Index: Das, Biswanath; Kumar, Rathod Aravind; Thirupathi, Ponnaboina; Suneel, Kanaparthy; Sunitha, Pothkan Canadian Journal of Chemistry, 2008 , vol. 86, # 7 p. 709 - 713

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Citation Number: 4

Abstract

Aldehydes and imines can efficiently undergo nucleophilic addition reaction with allyltributylstannane in the presence of phosphomolybdic acid supported on silica (PMA/SiO2) under solvent free-conditions to form the corresponding homoallyl alcohols and amines respectively at room temperature in excellent yields. The catalyst can be easily recovered and re-used. Key words: homoallyl alcohol, homoallyl amine, phosphomolybdic ...