The Journal of Chemical Physics

Mass??Spectrometric Studies of the Synthesis, Energetics, and Cryogenic Stability of the Lower Boron Hydrides

JH Wilson, HA McGee Jr

Index: Wilson, J. H.; McGee, H. A. Journal of Chemical Physics, 1967 , vol. 46, p. 1444 - 1453

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Citation Number: 37

Abstract

Ionization??efficiency measurements on species produced in the pyrolysis of B2H6 have led to A (B+), A (BH+), A (BH2+), A (BH3+), and A (B2H5+) from B2H6 and to A (B+), A (BH+), A (BH2+), and I (BH3) from BH3. These experimental results have permitted a rather complete development of the energetics of the BH3; B2H6 system and its related radicals and ions, including the important symmetric dissociation energy, D (BH3–BH3), which was found to ...