Reaction of chloromethyliso (thio) cyanato (thio) phosphonates (-phosphinates) with phenol, ethanol, and thiols

…, RK Bagautdinova, AA Shaimardanova…

Index: Khailova; Bagautdinova; Shaimardanova; Krepysheva; Pudovik; Chmutova; Azancheev; Musin Russian Journal of General Chemistry, 2004 , vol. 74, # 9 p. 1335 - 1340

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Abstract

Abstract (Chloromethyl) isocyanatophosphonates (-phosphinates) take up phenol to form carbamates whose β-cleavage gives rise to phenyl (chloromethyl) phosphonates (- phosphinates).(Chloromethyl)(thio) phosphinic-(phosphonic) isothiocyanates react with phenol at 20° C in the absence of catalyst to afford phenyl phosphinates (-phosphonates).( Alkylsulfanyl) carbamates formed by addition of thiols to (chloromethyl) iso (thio) ...