Phytochemistry

Chemical syntheses of caffeoyl and 5-OH coniferyl aldehydes and alcohols and determination of lignin O-methyltransferase activities in dicot and monocot species

F Chen, P Kota, JW Blount, RA Dixon

Index: Chen, Fang; Kota, Parvathi; Blount, Jack W.; Dixon, Richard A. Phytochemistry, 2001 , vol. 58, # 7 p. 1035 - 1042

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Citation Number: 28

Abstract

To investigate the substrate preferences of O-methyltransferases in the monolignol biosynthetic pathways, caffeoyl and 5-hydroxy coniferyl aldehydes were synthesized by a new procedure involving a Wittig reaction with the corresponding hydroxybenzaldehydes. The same procedure can also be used to synthesize caffeoyl and 5-hydroxyconiferyl alcohols. Relative O-methyltransferase activities against these substrates were ...