Abstract: Net allylic amination of cis-alkenes was accomplished by a two-step procedure that proceeded with excellent regie and absolute stereochemical control in moderate to good chemical yield. Reaction of alkenes with the N-sulfinylcarbamate of tranr-2- phenylcyclohexanol (l) in the presence of SnCl, provided allylic sulfinamides 2 with absolute stereochemical control at both sulfur and carbon stereocenters. Subsequent conversion of ...
