Bulletin of the Chemical Society of Japan

Dynamic NMR as a Nondestructive Method for Determination of Rates of Dissociation. XV. Dissociation of Thioether and Ether Ligands in Tin (IV) and Boron …

M Oki, Y Yamada

Index: Oki, Michinori; Yamada, Yasuhisa Bulletin of the Chemical Society of Japan, 1988 , vol. 61, p. 1191 - 1194

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Citation Number: 11

Abstract

The rates of dissociation of thioether ligands which are imbedded in organotin (IV) compounds, such as trichloro [o-(ethylthiomethyl) phenyl] stannane, were determined by the dynamic NMR method. The dynamic processes of the corresponding ether ligands was too fast to detect as the change in line shapes in 1 H NMR spectra. All the boron compounds examined, which possessed similar structures to the stannane and were of the boronate ...