Journal of Organometallic Chemistry

Electrochemical and ESR kinetics studies of electron transfer in the system bis (η6-Arene) Chromium (0)/bis (η6-Arene) Chromium (I)

TTT Li, CH Brubaker

Index: Li, T. T.- T.; Brubaker, C.H. Journal of Organometallic Chemistry, 1981 , vol. 216, # 2 p. 223 - 234

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Abstract

Abstract The self-exchange rates and activation parameters in the (η 6-arene) 2 Cr 0/(η 6- arene) 2 Cr I systems (where arene= toluene, benzene, methoxylbenzene, biphenyl, ethylbenzoate and chlorobenzene) have been measured by the ESR line broaden ing technique in DMSO solvent. The one-electron reduction was investigated by cyclic voltammetry for the series of substituted complexes of (η 6-arene) 2 Cr I. A linear ...